Polymer branching is an important molecular parameter since it affects various macroscopic polymer properties such as crystallinity, melting temperature, toughness, ductility, and optical clarity.1-2 Two types of branching are recognized: long-chain branching (LCB) wherein the molar mass of the branches is greater than the entanglement molar mass, and short-chain branching (SCB) wherein the molar mass of the branches is smaller than the entanglement molar mass.




